How to Test for Available Chlorine? Accurate Methods & Best Portable Tester

2025.12.30
ERUN

Available chlorine is one of the most critical indicators in water quality control. Whether you are managing drinking water, wastewater, industrial processes, swimming pools, or aquaculture systems, accurately testing for available chlorine is essential to ensure safety, compliance, and effective disinfection.

In this article, we explain what available chlorine is, review the most common testing methods, and introduce a reliable portable solution—the ERUN-SP7 portable multi-parameter water quality tester—for fast and accurate on-site chlorine measurement.

What Is Available Chlorine and Why Is It Important to Test?

Definition of Available Chlorine in Water Testing

Available chlorine refers to the portion of chlorine in water that is chemically active and capable of disinfecting microorganisms. It generally includes free chlorine (hypochlorous acid and hypochlorite ions) and combined chlorine (chloramines), depending on the testing method used. In practice, available chlorine is often assessed through residual chlorine or total chlorine measurements.

Why Available Chlorine Testing Matters for Water Safety

Chlorine is widely used as a disinfectant because of its effectiveness and low cost. However, insufficient available chlorine may lead to microbial contamination, while excessive chlorine can cause corrosion, unpleasant taste and odor, and health risks. Accurate available chlorine testing is therefore essential for:

Drinking water treatment and distribution

Wastewater disinfection

Industrial process water control

Swimming pools and recreational water

Aquaculture and environmental monitoring

How to Test for Available Chlorine? Common Methods Explained

DPD Colorimetric Method – The Most Widely Used Approach

The DPD (N, N-diethyl-p-phenylenediamine) colorimetric method is the most commonly used technique for testing available chlorine. Chlorine reacts with the DPD reagent to produce a pink or red color, and the intensity of the color corresponds to chlorine concentration.

Advantages:

Fast and easy to use

Suitable for portable instruments

Good accuracy for routine monitoring

Limitations:

 can be affected by turbidity or color

Requires proper reagent handling

Iodometric Titration – Laboratory Reference Method

Iodometric titration is a classical laboratory method used for high-accuracy chlorine analysis. Chlorine oxidizes iodide to iodine, which is then titrated with sodium thiosulfate.

Best suited for:

Laboratory reference testing

High-concentration chlorine samples

However, this method is time-consuming and not ideal for on-site measurements.

Portable Instrument Testing vs Test Kits

Compared with visual test kits, portable chlorine testers offer higher precision, digital readings, and better repeatability. They are ideal for field testing where speed, accuracy, and data reliability are critical.

Key Parameters to Measure Along with Available Chlorine

Free Chlorine vs Total Chlorine vs Available Chlorine

Free chlorine: Most effective disinfectant form

Total chlorine: Free chlorine + combined chlorine

Available chlorine: Indicates overall disinfecting capacity

Choosing the right parameter depends on regulatory requirements and application scenarios.

Related Water Quality Indicators Affecting Chlorine Accuracy

Other water parameters can influence chlorine measurement and effectiveness, including:

pH

Turbidity

Color

COD

Ammonia nitrogen

Measuring these parameters together provides a more complete picture of water quality.

What Should You Look for in an Available Chlorine Tester?

Accuracy, Repeatability, and Optical Stability

A reliable, available chlorine tester should offer:

High measurement accuracy

Low repeatability error (≤3%)

stable optical system with minimal drift

These factors ensure consistent and trustworthy results in long-term monitoring.

Multi-Parameter Capability and Expandability

Modern water analysis often requires testing multiple parameters. A multi-parameter water quality tester reduces equipment costs, improves efficiency, and supports comprehensive water management.

ERUN Portable Multi-Parameter Water Quality Tester (ERUN-SP7)

How ERUN-SP7 Tests Available Chlorine and Total Chlorine

The ERUN-SP7 from Erun is a portable multi-parameter water quality tester designed for accurate and on-site analysis. It supports testing of residual chlorine, total chlorine, and chlorine dioxide, making it highly suitable for available chlorine monitoring across different applications.

Supported Parameters and Customizable Testing Items

Beyond chlorine, ERUN-SP7 can measure a wide range of parameters, including:

COD

Ammonia nitrogen

Total phosphorus

Total nitrogen

Turbidity and color

Copper, chromium, manganese, iron, zinc, aluminum

Cyanide, phosphate, sulfate, nitrite, and hardness

The instrument can also be expanded and customized according to user requirements, covering heavy metals and inorganic salts.

Technical Advantages of ERUN-SP7 for Chlorine Testing

Key performance highlights include:

Repeatability: ≤3%

Optical stability: Absorbance drift <0.002A within 20 minutes

Reading modes: Concentration, absorbance, and light transmittance

These features ensure stable, accurate, and flexible chlorine testing in both field and laboratory environments.

Contact us today to get detailed specifications or request a quotation:
Email: stella@xayingrun.com 
WhatsApp:(+86-18189135710)

Applications of Available Chlorine Testing Across Industries

Drinking Water, Wastewater & Industrial Water Treatment

Available chlorine testing ensures disinfection efficiency and regulatory compliance throughout water treatment processes.

Swimming Pools, Aquaculture & Environmental Monitoring

Accurate chlorine control protects public health, aquatic life, and ecological balance while preventing over-chlorination.

Summary – What Is the Best Way to Test for Available Chlorine?

The best way to test for available chlorine is by combining a reliable colorimetric method with a high-quality portable instrument. The ERUN-SP7 portable multi-parameter water quality tester offers accurate chlorine analysis, excellent optical stability, and extensive parameter coverage, making it a dependable solution for professionals.

For users seeking accurate, efficient, and customizable chlorine testing, ERUN-SP7 from erunwas.com is a smart and future-proof choice.


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stella@xayingrun.com